Download/Embed scientific diagram | Diagrama de Pourbaix del hierro [12] y voltaje en función del pH (línea azul). from publication: Síntesis de nanopartículas. and radionuclide transport in groundwater. The most well-known studies on comprehensive Eh-pH diagrams are those of Pourbaix () and. Brookins ( ). Aluminum E-pH (Pourbaix) Diagram. The E-pH diagram of aluminum is one of the simplest E-pH diagrams. It will be used here to demonstrate how such.

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Above this line, water will be oxidized to form oxygen gas, and it will usually not be possible to pass beyond this line as long as there is still water present to be oxidized. United States Government Printing Office. The following Figure illustrates the results that were computed by setting the concentrations of soluble species at decreasing values of one 10 0one hundredth 10 -2one in ten thousand 10 -4and one in a million 10 The following Figure pourbaox the results of such computation for aluminum in the presence of water at 25 o C when the activities of all species considered were set at value unity.

While such diagrams can be drawn for any chemical system, it is important to note that the addition of a metal binding agent ligand will often modify the diagram. Passivation occurs when the metal forms a stable coating of an oxide or other salt on its surface, the best example being the relative stability of aluminium because of the alumina layer formed on its surface when exposed to pourbbaix.

Pourbaix diagram

Since there is no change in valence of the aluminum present in the two ionic species considered, the associated equilibrium is independent of the potential and the expression of that equilibrium can be derived in the following expression for standard conditions. By using the standard thermodynamic data from the literature, it is possible piurbaix calculate that the free energy of reaction is in fact equal to Retrieved from ” https: In many cases, the possible conditions in a system are limited by the stability region of water.


Pourbaix diagrams have several pourbais, for example in corrosion studies, geoscience and in environmental studies.

The equation must be balanced for M, H, O and charge. Below this line, water will be reduced to hydrogen, and it will usually not be possible to pass beyond this line as long as there fiagrama still water present to be reduced.

A simplified Pourbaix diagram indicates regions of “Immunity”, “Corrosion” and “Passivity”, instead of the stable species. The usefulness of this graphical representation of thermodynamic data for corrosion studies was discussed by Pourbaix who showed three possible states of a metallic material: Usually, the activity of a species is approximated as equal to the concentration for soluble species or partial pressure for gases.

Aluminum E-pH (Pourbaix) diagram

The “H” stands for hydrogen, although other standards may diqgrama used, and they are for room temperature only. This will vary with temperature. In these cases, pE is used instead of E H. The diagrams are named after Marcel Pourbaix —the Russian -born, Belgian chemist who invented them. The same values should be used for all species present in the system.

It is customary to use the lowest boundary 10 -6 as a practical indication of the corrosion stability of a metal and poyrbaix solid products Figure 4. Predominant ion boundaries are represented by lines.

In the Pourbaix diagram for uranium, the limits of stability of water are marked by the two dashed green lines, and the stability region for water falls diaggama these lines. The reaction equation is found to be:.


As such a Pourbaix diagram can be read much like a standard phase diagram with a different set of axes. Pourbix vertical axis is labeled E H for the voltage potential with respect to the standard hydrogen electrode SHE as calculated by the Nernst equation.

Environmental Chemistry – a global perspective 3rd ed. The apparent stability of the solid species considered gradually recedes as lower values of soluble species are used in the calculations. Using the Nernst equation as above, but with an E 0 of 1. In other projects Wikimedia Commons. A base-balanced equation can be converted to an acid-balanced equation using the equilibrium constant for the self-ionization of waterand poubraix acid-balanced equations are considered below.

Pourbaix diagrams are widely used to describe the chemical behaviour of chemical species in the hydrosphere. They thus give a guide to the stability of a particular metal in a specific environment.

Pourbaix diagrams are also known as E H -pH diagrams due to the labeling of the two axes.

Diagrama de Pourbaix

In addition, changes in temperature and concentration of solvated ions in solution will shift the equilibrium lines in accordance with the Nernst equation.

E-pH diagram showing the soluble species of aluminum in water at 25 o C. Immunity means that the metal is not attacked, while corrosion shows that general attack will occur.

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